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Optical diffuse reflectance UV/Vis/NIR spectroscopy revealed a nearly linear contraction of the optical band gap with increasing Se content.Learn more, including about available controls: Cookies Policy.Photoluminescence and photomodulated reflectivity measurements of Zn OSe alloys are used to demonstrate a splitting of the valence band due to the band anticrossing interaction between localized Se states and the extended valence band states of the host Zn O matrix.It has been shown previously that the electronic structure of such highly mismatched alloys (HMAs) is determined by an anticrossing interaction between localized states of the minority and extended band states of the majority component of the alloy. An obvious transition point from ferrimagnetism or ferromagnetism to antiferromagnetism cannot be observed in both systems.

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